CobaltMaghrebV1, Main, Exploration, bibRecord, 000245

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)

Identifieur interne : 000245 ( Main/Exploration ); précédent : 000244; suivant : 000246

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)

Auteurs : Rafika Bouchene [Algérie] ; Sofiane Bouacida [Algérie] ; Fadila Berrah [Algérie] ; Ratiba Belhouas [Algérie] ; Hocine Merazig [Algérie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2013.

RBID : PMC:3569217

Abstract

In the title compound, [Co(C₅H₄N₃O₂)₂(H₂O)₂], the Co^II atom is situated on a twofold rotation axis and is N,O-chelated by two 3-aminopyrazine-2-carboxylate anions and additionally bonded to the O atoms of two water molecules, leading to a slightly distorted octahedral coordination environment. The crystal packing is dominated by intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water molecules and amino groups as donors and carboxylate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intramolecular N—H⋯O hydrogen bond is also observed.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217

DOI: 10.1107/S1600536813002183
PubMed: 23424419
PubMed Central: 3569217

Affiliations:

Algérie

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Bis(3-aminopyrazine-2-carboxylato-κ<sup>2</sup>
<italic>N</italic>
<sup>1</sup>
,<italic>O</italic>
)diaquacobalt(II)</title>
<author><name sortKey="Bouchene, Rafika" sort="Bouchene, Rafika" uniqKey="Bouchene R" first="Rafika" last="Bouchene">Rafika Bouchene</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bouacida, Sofiane" sort="Bouacida, Sofiane" uniqKey="Bouacida S" first="Sofiane" last="Bouacida">Sofiane Bouacida</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Berrah, Fadila" sort="Berrah, Fadila" uniqKey="Berrah F" first="Fadila" last="Berrah">Fadila Berrah</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Belhouas, Ratiba" sort="Belhouas, Ratiba" uniqKey="Belhouas R" first="Ratiba" last="Belhouas">Ratiba Belhouas</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">PMC</idno>
<idno type="pmid">23424419</idno>
<idno type="pmc">3569217</idno>
<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569217</idno>
<idno type="RBID">PMC:3569217</idno>
<idno type="doi">10.1107/S1600536813002183</idno>
<date when="2013">2013</date>
<idno type="wicri:Area/Pmc/Corpus">000361</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Corpus" wicri:corpus="PMC">000361</idno>
<idno type="wicri:Area/Pmc/Curation">000360</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Curation">000360</idno>
<idno type="wicri:Area/Pmc/Checkpoint">000211</idno>
<idno type="wicri:explorRef" wicri:stream="Pmc" wicri:step="Checkpoint">000211</idno>
<idno type="wicri:source">PubMed</idno>
<idno type="wicri:Area/PubMed/Corpus">000035</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">000035</idno>
<idno type="wicri:Area/PubMed/Curation">000035</idno>
<idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">000035</idno>
<idno type="wicri:Area/PubMed/Checkpoint">000035</idno>
<idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">000035</idno>
<idno type="wicri:Area/Ncbi/Merge">000245</idno>
<idno type="wicri:Area/Ncbi/Curation">000245</idno>
<idno type="wicri:Area/Ncbi/Checkpoint">000245</idno>
<idno type="wicri:Area/Main/Merge">000246</idno>
<idno type="wicri:Area/Main/Curation">000245</idno>
<idno type="wicri:Area/Main/Exploration">000245</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main">Bis(3-aminopyrazine-2-carboxylato-κ<sup>2</sup>
<italic>N</italic>
<sup>1</sup>
,<italic>O</italic>
)diaquacobalt(II)</title>
<author><name sortKey="Bouchene, Rafika" sort="Bouchene, Rafika" uniqKey="Bouchene R" first="Rafika" last="Bouchene">Rafika Bouchene</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Bouacida, Sofiane" sort="Bouacida, Sofiane" uniqKey="Bouacida S" first="Sofiane" last="Bouacida">Sofiane Bouacida</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Berrah, Fadila" sort="Berrah, Fadila" uniqKey="Berrah F" first="Fadila" last="Berrah">Fadila Berrah</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie Appliquée et Technologie des Matériaux LCATM, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Belhouas, Ratiba" sort="Belhouas, Ratiba" uniqKey="Belhouas R" first="Ratiba" last="Belhouas">Ratiba Belhouas</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
<affiliation wicri:level="1"><nlm:aff id="c">Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Université Mentouri Constantine 25000,<country>Algeria</country>
</nlm:aff>
<country xml:lang="fr">Algérie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
</analytic>
<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2013">2013</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en"><p>In the title compound, [Co(C<sub>5</sub>
H<sub>4</sub>
N<sub>3</sub>
O<sub>2</sub>
)<sub>2</sub>
(H<sub>2</sub>
O)<sub>2</sub>
], the Co<sup>II</sup>
 atom is situated on a twofold rotation axis and is <italic>N</italic>
,<italic>O</italic>
-chelated by two 3-aminopyrazine-2-carboxylate anions and additionally bonded to the O atoms of two water molecules, leading to a slightly distorted octahedral coordination environment. The crystal packing is dominated by intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonding involving the water molecules and amino groups as donors and carboxylate O atoms, as well as the non-coordinating heterocyclic N atoms as acceptors, resulting in a three-dimensional network. An intramolecular N—H⋯O hydrogen bond is also observed.</p>
</div>
</front>
<back><div1 type="bibliography"><listBibl><biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
<biblStruct></biblStruct>
</listBibl>
</div1>
</back>
</TEI>
<affiliations><list><country><li>Algérie</li>
</country>
</list>
<tree><country name="Algérie"><noRegion><name sortKey="Bouchene, Rafika" sort="Bouchene, Rafika" uniqKey="Bouchene R" first="Rafika" last="Bouchene">Rafika Bouchene</name>
</noRegion>
<name sortKey="Belhouas, Ratiba" sort="Belhouas, Ratiba" uniqKey="Belhouas R" first="Ratiba" last="Belhouas">Ratiba Belhouas</name>
<name sortKey="Berrah, Fadila" sort="Berrah, Fadila" uniqKey="Berrah F" first="Fadila" last="Berrah">Fadila Berrah</name>
<name sortKey="Berrah, Fadila" sort="Berrah, Fadila" uniqKey="Berrah F" first="Fadila" last="Berrah">Fadila Berrah</name>
<name sortKey="Bouacida, Sofiane" sort="Bouacida, Sofiane" uniqKey="Bouacida S" first="Sofiane" last="Bouacida">Sofiane Bouacida</name>
<name sortKey="Bouacida, Sofiane" sort="Bouacida, Sofiane" uniqKey="Bouacida S" first="Sofiane" last="Bouacida">Sofiane Bouacida</name>
<name sortKey="Bouchene, Rafika" sort="Bouchene, Rafika" uniqKey="Bouchene R" first="Rafika" last="Bouchene">Rafika Bouchene</name>
<name sortKey="Merazig, Hocine" sort="Merazig, Hocine" uniqKey="Merazig H" first="Hocine" last="Merazig">Hocine Merazig</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000245 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000245 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     PMC:3569217
   |texte=   Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)
}}

Pour générer des pages wiki

HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i   -Sk "pubmed:23424419" \
       | HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd   \
       | NlmPubMed2Wicri -a CobaltMaghrebV1

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

Serveur d'exploration sur le cobalt au Maghreb

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Bis(3-amino­pyrazine-2-carboxyl­ato-κ2N1,O)diaqua­cobalt(II)

Bis(3-amino­pyrazine-2-carboxyl­ato-κ2N1,O)diaqua­cobalt(II)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)

Bis(3-aminopyrazine-2-carboxylato-κ2N1,O)diaquacobalt(II)